| Round | Overall | Player |
|---|---|---|
| 1 | 12th | OF Grady Sizemore Cle |
| 2 | 13th | OF Vladimir Guerrero LAA |
| 3 | 36th | SP Chris Carpenter StL |
| 4 | 37th | SP Carlos Zambrano ChN |
| 5 | 60th | 1B Todd Helton Col |
| 6 | 61st | 3B Scott Rolen StL |
| 7 | 84th | SS Rafael Furcal LAD |
| 8 | 85th | SP Jason Schmidt LAD |
| 9 | 108th | OF Raul Ibanez Sea |
| 10 | 109th | SP Adam Wainwright StL |
| 11 | 132nd | 2B Jeff Kent LAD |
| 12 | 133rd | RP Jason Isringhausen StL |
| 13 | 156th | DH Mike Piazza Oak |
| 14 | 157th | SP Mark Buehrle ChA |
| 15 | 180th | C Russell Martin LAD |
| 16 | 181st | SP Cliff Lee Cle |
| 17 | 204th | 3B Edwin Encarnacion Cin |
| 18 | 205th | OF Moises Alou NYN |
| 19 | 228th | OF Aaron Rowand Phi |
| 20 | 229th | 1B Ryan Shealy KC |
| 21 | 252nd | SP Kip Wells StL |
| 22 | 253rd | 2B Mark DeRosa ChN |
| 23 | 276th | SP Randy Wolf SD |
| 24 | 277th | SS Alex Gonzalez Cin |
| 25 | 300th | SP Mark Mulder StL |
| 26 | 301st | C Rod Barajas Phi |
| 27 | 324th | SP Chad Billingsley LAD |
| 28 | 325th | OF Corey Hart Mil |
| 29 | 348th | RP Braden Looper StL |