| Round | Overall | Player |
|---|---|---|
| 1 | 5th | OF Ryan Braun Mil |
| 2 | 20th | 1B Kendrys Morales LAA |
| 3 | 29th | 2B Dustin Pedroia Bos |
| 4 | 44th | OF Carlos Gonzalez Col |
| 5 | 53rd | 2B Brian Roberts Bal |
| 6 | 68th | SP Clayton Kershaw LAD |
| 7 | 77th | SP Chad Billingsley LAD |
| 8 | 92nd | SP Wandy Rodriguez Hou |
| 9 | 101st | OF Andrew McCutchen Pit |
| 10 | 116th | RP Brian Wilson SF |
| 11 | 125th | RP Rafael Soriano TB |
| 12 | 140th | RP Frank Francisco Tex |
| 13 | 149th | SP David Price TB |
| 14 | 164th | RP Billy Wagner Atl |
| 15 | 173rd | SP Wade Davis TB |
| 16 | 188th | SS Elvis Andrus Tex |
| 17 | 197th | SS Marcos Scutaro Bos |
| 18 | 212th | C Buster Posey SF |
| 19 | 221st | SP Jonathan Sanchez SF |
| 20 | 236th | RP Neftali Feliz Tex |
| 21 | 245th | 3B Casey Blake LAD |
| 22 | 260th | SP Mat Latos SD |
| 23 | 269th | SP Jorge de la Rosa Col |
| 24 | 284th | C Carlos Santana Cle |
| 25 | 293rd | 1B Troy Glaus Atl |
| 26 | 308th | OF Mark DeRosa SF |
| 27 | 317th | OF Cody Ross Fla |
| 28 | 332nd | OF Drew Stubbs Cin |
| 29 | 341st | 3B Edwin Encarnacion Oak |