| Round | Overall | Player |
|---|---|---|
| 1 | 8th | 1B Joey Votto Cin |
| 2 | 17th | SP Justin Verlander Det |
| 3 | 32nd | SP Jered Weaver LAA |
| 4 | 41st | SP Matt Cain SF |
| 5 | 56th | 2B Ben Zobrist TB |
| 6 | 65th | SS Ian Desmond Was |
| 7 | 80th | OF Melky Cabrera Tor |
| 8 | 89th | DH Adam Dunn ChA |
| 9 | 104th | OF Carlos Beltran NYA |
| 10 | 113th | RP Mariano Rivera NYA |
| 11 | 128th | OF Carl Crawford LAD |
| 12 | 137th | SP Josh Johnson Tor |
| 13 | 152nd | SP Mike Minor Atl |
| 14 | 161st | RP Addison Reed Ari |
| 15 | 176th | 3B Mike Moustakas KC |
| 16 | 185th | RP Chris Perez LAD |
| 17 | 200th | OF Michael Cuddyer Col |
| 18 | 209th | OF Torii Hunter Det |
| 19 | 224th | SP Ryan Dempster Bos |
| 20 | 233rd | 3B Trevor Plouffe Min |
| 21 | 248th | C Ryan Doumit Atl |
| 22 | 257th | OF Ryan Ludwick Cin |
| 23 | 272nd | 2B Gordon Beckham ChA |
| 24 | 281st | SP Matt Garza Tex |
| 25 | 296th | OF Michael Saunders Sea |
| 26 | 305th | C Chris Iannetta LAA |
| 27 | 320th | SS Jean Segura Mil |
| 28 | 329th | SP Barry Zito SF |
| 29 | 344th | SP Edison Volquez LAD |