| Round | Overall | Player |
|---|---|---|
| 1 | 7th | 1B Joey Votto Cin |
| 2 | 18th | 3B David Wright NYN |
| 3 | 31st | OF Shin-Soo Choo Tex |
| 4 | 42nd | SS Jose Reyes Tor |
| 5 | 55th | OF Mark Trumbo Ari |
| 6 | 66th | SP Jordan Zimmermann Was |
| 7 | 79th | OF Josh Hamilton LAA |
| 8 | 90th | SP Jered Weaver LAA |
| 9 | 103rd | SP C.J. Wilson LAA |
| 10 | 114th | OF Starling Marte Pit |
| 11 | 127th | 3B Anthony Rendon Was |
| 12 | 138th | DH Billy Butler KC |
| 13 | 151st | SP Ivan Nova NYA |
| 14 | 162nd | RP Casey Janssen Tor |
| 15 | 175th | RP Ernesto Frieri Pit |
| 16 | 186th | 1B Ryan Howard Phi |
| 17 | 199th | SP Dillon Gee NYN |
| 18 | 210th | OF Christian Yelich Mia |
| 19 | 223rd | 3B Chris Johnson Atl |
| 20 | 234th | 1B Corey Hart Sea |
| 21 | 247th | SP Taijuan Walker Sea |
| 22 | 258th | 2B Brian Roberts NYA |
| 23 | 271st | RP Nathan Jones ChA |
| 24 | 282nd | SP Charlie Morton Pit |
| 25 | 295th | SP Erik Johnson ChA |
| 26 | 306th | SS Erick Aybar LAA |
| 27 | 319th | SP Jeremy Guthrie KC |
| 28 | 330th | C John Jaso Oak |
| 29 | 343rd | C Wellington Castillo ChN |