| Round | Overall | Player |
|---|---|---|
| 1 | 10th | OF Yasiel Puig LAD |
| 2 | 15th | 1B Joey Votto Cin |
| 3 | 34th | OF Carlos Gonzalez Col |
| 4 | 39th | OF Bryce Harper Was |
| 5 | 58th | 3B David Wright NYN |
| 6 | 63rd | 2B Ian Kinsler Det |
| 7 | 82nd | SS Jhonny Peralta StL |
| 8 | 87th | SP Sonny Gray Oak |
| 9 | 106th | RP Cody Allen Cle |
| 10 | 111th | RP Steve Cishek Mia |
| 11 | 130th | 1B Justin Morneau Col |
| 12 | 135th | SP Michael Wacha StL |
| 13 | 154th | 1B Eric Hosmer KC |
| 14 | 159th | C Salvador Perez KC |
| 15 | 178th | SP Danny Duffy KC |
| 16 | 183rd | OF Avisail Garcia ChA |
| 17 | 202nd | 2B Ben Zobrist KC |
| 18 | 207th | C Miguel Montero ChN |
| 19 | 226th | SP Mike Leake SF |
| 20 | 231st | 3B Chase Headley NYA |
| 21 | 250th | SP Josh Collmenter Ari |
| 22 | 255th | SS Andrelton Simmons Atl |
| 23 | 274th | OF Allen Craig Bos |
| 24 | 279th | RP Tyler Clippard NYN |
| 25 | 298th | SP Wade Miley Bos |
| 26 | 303rd | OF Carl Crawford LAD |
| 27 | 322nd | SP Kyle Lohse Mil |
| 28 | 327th | SP Jake Odorizzi TB |
| 29 | 346th | SP Jason Vargas KC |